So what's the mole fraction of B in the gas phase? 那么B在气相中的摩尔分数是多少?
And the point here is that unlike this case, where you have a linear relationship, the relationship between the pressure and the liquid mole fraction isn't linear. 关键点在于与这个情况不同,这里我们有的是一个线性的关系,压强和液相摩尔分数的关系不是线性的,我们仍然可以把它画出来。
Well it's the mole fraction of A in the gas. 这是气体中A的摩尔分数。
And in terms of the molar fractions, it's the total pressure squared, times the mole fraction of NO2 squared, divided by the total pressure to the first power. 写成摩尔分数的函数,总压强的平方,乘以NO2摩尔分数的平方,除以总压强。
So this xB, which is the liquid mole fraction, is now yB, the gas mole fraction. 所以xB,液态时的摩尔分数,现在是yB,气态摩尔分数。
That the vapor pressure of the solute is related to the mole fraction in the solution. 溶质的蒸汽压,和溶液中溶质的摩尔分数成正比。
So this is the one that's showing us the mole fraction in the liquid phase. 这是告诉我们,液相摩尔分数的曲线。
And then you have one non-linear relationship there for the mole fraction of the gas. 然后你们会遇到气体摩尔分数,是非线性关系的情况。
The pressures over the pure liquid A and B at the limits of mole fraction of B being zero and one. 纯液相A和B的压强,在B的摩尔分数为零和一的极限时的值。
So, here is the liquid mole fraction at temperature two. 好,这是二点温度下的液态摩尔分数。
Very small mole fraction. 摩尔分数很小。
For a given media, and at a constant total pressure and temperature, the partial pressure of oxygen is proportional to oxygen mole fraction. 对一个给定的媒介,在恒定的总压和温度下,局部压力与氧的克分子数成比例。
The gas mole fraction. 气体摩尔分数。
And if we go over here, this is telling us about the mole fraction in the gas phase. 如果我们到达那,它告诉了我们气相的摩尔分数。
And for each component we have to describe its mole fraction in that particular phase. 对每一个组分我们都要知道,它在各个相中的摩尔分数。
OK, so we're going to look at temperature and mole fraction phase diagrams. 好,让我们看看温度,和摩尔分数相图。
If we plot this versus xB, this is mole fraction of B in the liquid going from zero to one. 如果我们把它化成xB的函数,这是液相B的摩尔分数,从零到一。
So, for each phase alpha, we have to describe its mole fraction. 对每个相α,我们需要它的摩尔分数去描述。
Which is the form of the equilibrium constant not in terms of the partial pressures, but in terms of the mole fraction. 它不是与分压有关的,平衡常数,而是与摩尔分数有关。
You decrease the mole fraction of the less volatile material in the gas phase. 更不易挥发的物质,在气相中的,摩尔分数减小了。
And you'll have some different mole fraction than you started with before. 你会和之前开始的时候,有不同的摩尔分数。
So that means just reading off it, this is xB, that's the liquid mole fraction. 直接读出来,可得是xB,是液相摩尔分数。
B So it's got some mole fraction of B. 其中有一些摩尔分数的。
And let's say the mole fraction of A in each of the liquid and gas phases, right? 我们在液相和,气相中都有A的摩尔分数,对吗?
So that the vapor pressure of CS2 is related to the mole fraction of CS2 times the vapor pressure of CS2 if it was pure. 所以CS2的蒸汽压2,与CS2的摩尔分数2,和纯的CS2溶液蒸汽压的积成正比。
Now, of course, since this is a mole fraction, it's always between zero and one. 现在,当然,由于这是摩尔分数,它总是处于零到一之间。
The constraint is that the sum of all the mole factions has to be equal to one That's what it is, to be a mole fraction. 约束条件是,所有摩尔分数之和等于1。,这就是摩尔分数的意义。
So that's our mole fraction of B. 这就是B的摩尔分数。
And then I have a non-linear relationship between the pressure and the mole fraction in the gas phase. 然后我有压强,和气相摩尔分数之间的非线性关系。
So this is the mole fraction of the liquid. 这是液相的摩尔分数。